Heat half of the oil in a large skillet over medium heat.
Add onion and sauté until soft. Add bell pepper, cumin, oregano, and tomatoes; cook until bell pepper has softened.
Stir in vinegar, jalapeno, salt and pepper; cook for 1 minute.
Remove skillet from heat and transfer mixture to a serving bowl. Evenly sprinkle pork chops with paprika and cayenne pepper then season with salt and pepper to taste.
In the same skillet, heat remaining olive oil over medium-high heat. Add pork chops and brown on both sides.
Continue cook chops till done, 3 to 4 minutes per side.
Serve chops with tomato and jalapeno relish.